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Definition: free energy from Hawley's Condensed Chemical Dictionary

(ΔG; Gibbs free energy). An exact thermodynamic quantity used to predict the maximum work obtainable from the spontaneous transformation of a given system. It also provides a criterion for the spontaneity of a transformation or reaction and predicts the greatest extent to which the reaction can occur, i.e., its maximum yield. Transformation of a system can be brought about by either heat or mechanical work. Free energy is derived from the internal energy and entropy of a system in accordance with the laws of thermodynamics.

See also enthalpy.

Summary Article: free energy
from The Columbia Encyclopedia

or Gibbs free energy, quantity derived from the relationships between heat and work studied in thermodynamics and used as a measure of the relative stability of a physical or chemical system, i.e., the tendency of the system to react or change. If the change in free energy, ΔG, is negative, the transformation of the system will occur spontaneously, since transitions in which the energy decreases are favored, whereas those in which it increases (ΔG positive) are not. The change in free energy for a given process at a particular temperature depends on three factors, as seen from the equation ΔG = ΔH - TΔS, where ΔH is the change in the enthalpy of the system, T is the temperature in degrees Kelvin, and ΔS is the change in entropy. A negative value of the enthalpy change indicates a decrease in the heat content of the system and contributes to a favorable value of the free energy; a positive entropy change indicates a decrease in the orderliness of the system and also contributes to a favorable value of the free energy, since a system tends to go from more ordered to less ordered states. It may happen that the change in enthalpy for the reaction is favorable but that of the entropy is unfavorable, or vice versa; in such a case the temperature is the deciding factor since it determines how much weight is given to the entropy change. For example, in the transition of liquid water to ice, the enthalpy change is favorable because heat is released in the process but the entropy change is unfavorable because the transition is to the more ordered, crystalline state. Below a temperature of 32degrees Fahrenheit (273 degrees Kelvin) the enthalpy term, ΔH, is larger and the process is spontaneous, but at higher temperatures the entropy term, TΔS, predominates, and the transition does not occur. Although the free energy indicates whether or not a given reaction will occur, it gives no information about the speed of such a reaction. The reaction of hydrogen with oxygen to form water has a favorable, negative, free energy, but the reaction rate is so slow that without the presence of a catalyst it is not observable. Scientists use tables listing the standard free energy, ΔG°, of various compounds; the standard free energy is the change in free energy when one mole of the compound is formed at 25degrees Celsius and 1 atmospheric pressure.

The Columbia Encyclopedia, © Columbia University Press 2017

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